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Smart inorganic/organic hybrid microgels: Synthesis and characterisation
M. Karg, T. Hellweg:
Journal of Materials Chemistry, 19, 8714-8727 (2009)
doi: 10.1039/B820292N

Responsive hybrid colloids containing both organic and inorganic components have been the subject of many investigations in recent years. These new materials combine the stimuli-responsiveness of some polymer-based colloids with the unique properties of inorganic nanoparticles. This article will review the different possible variations of such hybrid colloids. Moreover, synthetic approaches, methods of characterisation, and a few applications will be discussed. Due to the rather high number of recent publications dealing with hybrid materials based on a variety of polymers, we will mainly focus on responsive hybrid microgels made of poly(N-isopropyl-acrylamide) or poly(N-vinylcaprolactam) in aqueous media.


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